Lye concentration versus Water:lye ratio
|25||3.00||The most water in proportion to alkali that is typically used for soap.
Good for making liquid soap paste, shave soap, or hot process (HP) bar soap. Not recommended for cold process (CP) soap. CP soap with this much water may not form a stable emulsion and may separate in the mold. It is very likely to be far too soft for days after saponifying.
|28||2.57||Lowest lye concentration I recommend for cold process (CP) bar soap.
Pros: Good for recipes high in coconut oil that can overheat and crack. May work better for complicated swirls, depending on the soaper and the recipe. Cons: Soap is more likely to gel during saponification, which you may or may not want. Soap is more likely to show streaking and mottling (aka glycerin rivers). Higher chance of emulsification failure and separation in the mold. Soap may take several days to firm up enough to be removed from the mold.
|33||2.03||Good all-around choice for most CP recipes and many CP soap makers. Pros: Chance of gelling and "glycerin rivers" is reduced but may sometimes happen. Soap gets firmer in the mold faster. Cons: Soap may trace somewhat faster than with more water, but this is not a hard-and-fast result. The time to trace also depends on the fats and your soaping methods.|
|40||1.50||Good choice for 100% olive oil soap and other slow saponifying recipes. Pros: Chance of gelling and "glycerin rivers" is very low. Other pros and cons are same as for 33% lye concentration (2.03 water:lye ratio).|
A lye solution at a 50% lye concentration (1 part water to 1 part NaOH by weight) contains the least amount of water in proportion to alkali that can be realistically used. If you use less water than this, not all of the NaOH will dissolve.
Any soap recipe can be made using a 50% lye solution, but most soapers prefer to use more water.
Some soapers make a "masterbatch" lye solution using a 50% alkali concentration. They make enough of this solution each time to make at least several batches of soap. The masterbatch may be stored for weeks or months before it is fully used up.
If you start masterbatching your lye, be sure to store the solution in a place that is warmer than 65F / 18C to keep it fluid and pourable. If the temperature of a 50% NaOH solution falls below about 55F / 13C, some of the alkali will crystallize out of solution. If this happens, the mixture must be warmed and all of the alkali must be fully dissolved before you use this solution to make soap.
More about Water:Lye Ratio
This ratio is the weight units of water used for every 1 weight unit of lye.
The "lye" in the water:lye ratio can be NaOH or KOH or a mixture of both alkalis.
The weight units can grams or ounces or any other unit of weight. Just be consistent -- don't mix grams with ounces!
Some examples --
Water:lye ratio of 1.50 means there are 1.5 grams of water for every 1 gram of alkali.
Water:lye ratio of 2.33 means there are 2.33 grams of water for every 1 gram of alkali.
If you prefer ounces, substitute "ounce" wherever you see "gram" in these examples.
Because the lye weight is always "1," this "1" is not always shown, such as in this table, but sometimes the "1" is shown. For example, you might see a water:lye ratio of 1.5 that looks like these examples --
1.5 to 1
The math behind this table
Convert lye concentration to water:lye ratio --
Water:Lye Ratio = 100 / Lye concentration % - 1
Example: The lye concentration is 30%. What is the water:lye ratio?
Water:Lye Ratio = 100 / 30 - 1 = 3.333333 - 1 = 2.33 (answer rounded to 2 places)
Convert water:lye ratio to lye concentration --
Lye concentration % = Lye weight / (Lye weight + Water weight) X 100
Example: The water:lye ratio is 1.5, meaning 1.5 parts water to 1 part lye. What is the lye concentration?
Lye concentration % = 1 / (1 + 1.5) X 100 = 1 / 2.5 X 100 = 40%
To learn more about choosing the right amount of water for your soap recipe, see "Full water and other drippy myths"